Preheat your oven to 350°F. Line an 8-inch square pan with parchment paper, leaving enough of an overhang on two sides to lift the brownies out later
In a medium saucepan, combine the chocolate chips and unsalted butter and melt together over medium-low heat, stirring frequently with a silicone spatula
Meanwhile, in a small bowl, mix together the cocoa powder, espresso powder, and cinnamon if using
Once the chocolate and butter have fully melted, turn off the heat and immediately whisk in the cocoa mixture until smooth
In a stand mixer fitted with the paddle attachment, or in a large bowl with a hand mixer, beat the eggs, granulated sugar, brown sugar, and vanilla on medium speed until light, fluffy, and slightly thickened, about 4 minutes. You'll know it's ready when you can rub a bit of the mixture between two fingers and barely feel any sugar granules left
On low speed, slowly mix the melted chocolate mixture into the egg mixture, scraping down the bowl as needed so everything is fully combined
In a separate bowl, whisk together the flour, powdered milk if using, and salt. Add this to the wet ingredients on low speed (or using a rubber spatula) and mix just until no streaks of flour remain. Don't overmix